Ni 28

Nickel (Ni)

transition-metal
Period: 4 Group: 10 Block: s

Solid

Standard Atomic Weight

58.6934 u

Electron configuration

[Ar] 4s2 3d8

Melting point

1454.85 °C (1728 K)

Boiling point

2912.85 °C (3186 K)

Density

8912 kg/m³

Oxidation states

−2, −1, 0, +1, +2, +3, +4

Electronegativity (Pauling)

1.91

Ionization energy (1st)

Discovery year

1751

Atomic radius

135 pm

Details

Name origin German: kupfernickel (false copper).
Discovery country Sweden
Discoverers Axel Cronstedt

Nickel is a silvery transition metal of group 10, valued for corrosion resistance, strength at high temperature, and its ability to form useful alloys. It is ferromagnetic near room temperature and commonly occurs in the +2 oxidation state, although several other states are known in coordination chemistry. Natural nickel is mostly found in sulfide and laterite ores, and it is a key metal for stainless steels, superalloys, plating, catalysts, and rechargeable batteries.

Nickel is silvery white and takes on a high polish. It is hard, malleable, ductile, somewhat ferromagnetic, and a fair conductor of heat and electricity. It belongs to the iron-cobalt group of metals and is chiefly valuable for the alloys it forms.

The name derives from the German Nickel for "deceptive little spirit" because miners called mineral niccolite (NiAs) by the name Kupfernickel (false copper) because it resembled copper ores in appearance, but no copper was found in the ore. It was discovered by the Swedish metallurgist Axel-Frederik Cronstedt in 1751.

Nickel was discovered by the Swedish chemist Axel Fredrik Cronstedt in the mineral niccolite (NiAs) in 1751. Today, most nickel is obtained from the mineral pentlandite (NiS·2FeS). Most of the world's supply of nickel is mined in the Sudbury region of Ontario, Canada. It is believed that this large deposit of nickel ore is a result of an ancient meteor impact.

From the German word Nickel (Satan), and from kupfernickel, Old Nick's copper. Cronstedt discovered nickel in 1751 in kupfernickel (niccolite).

Images

Properties

Physical

Atomic radius (empirical) 135 pm
Covalent radius 124 pm
Van der Waals radius 163 pm
Metallic radius 115 pm
Density
Molar volume 0.0066 L/mol
Phase at STP solid
Melting point 1454.85 °C
Boiling point 2912.85 °C
Thermal conductivity 90.9 W/(m·K)
Specific heat capacity 0.444 J/(g·K)
Molar heat capacity 26.07 J/(mol·K)
Crystal structure fcc

Chemical

Electronegativity (Pauling) 1.91
Electronegativity (Allen) 1.88
Electron affinity
Ionization energy (1st)
Ionization energy (2nd)
Ionization energy (3rd)
Ionization energy (4th)
Ionization energy (5th)
Oxidation states −2, −1, 0, +1, +2, +3, +4
Valence electrons 10
Electron configuration
Electron configuration (semantic)

Thermodynamic

Heat of fusion 0.18116806 eV
Heat of vaporization 3.838939 eV
Heat of sublimation 4.457688 eV
Heat of atomization 4.457688 eV
Atomization enthalpy

Nuclear

Stable isotopes 5
Discovery year 1751

Abundance

Abundance (Earth's crust) 84 mg/kg
Abundance (ocean)

Reactivity

N/A

Crystal Structure

Lattice constant a 352 pm

Electronic Structure

Electrons per shell 2, 8, 16, 2

Identifiers

CAS number 7440-02-0
Term symbol
InChI InChI=1S/Ni
InChI Key PXHVJJICTQNCMI-UHFFFAOYSA-N

Electron Configuration Measured

Ion charge
Protons 28
Electrons 28
Charge Neutral
Configuration Ni: 3d⁸ 4s²
Electron configuration
Measured
[Ar] 3d⁸ 4s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁸ 4s²
Orbital diagram
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
8/10 2↑
Total electrons: 28 Unpaired: 2 ?

Atomic model

Protons 28
Neutrons 32
Electrons 28
Mass number 60
Stability Stable

Isotopes change neutron count, mass, and stability — not the electron configuration of a neutral atom.

Schematic atomic model, not to scale.

Atomic Fingerprint

Emission / Absorption Spectrum

25 / 50 (50 with intensity)
Measured
Emission Visible: 380–750 nm

Isotope Distribution

6026.2230%623.6346%611.1399%640.9255%Mass numberNatural abundance (%)
Mass numberAtomic mass (u)Natural abundanceHalf-life
60 Stable59.93078588 ± 0.0000005226.2230%Stable
61 Stable60.93105557 ± 0.000000521.1399%Stable
62 Stable61.92834537 ± 0.000000553.6346%Stable
64 Stable63.92796682 ± 0.000000580.9255%Stable
Measured

Phase / State

1 atm / 101.325 kPa
Solid 25 °C (298.15 K)

Reason: 1429.8 °C below melting point (1454.85 °C)

Melting point 1454.85 °C
Boiling point 2912.85 °C
Below melting by 1429.8 °C
0 K Current temperature: 25 °C 6000 K
Phase timeline

Schematic, not to scale

Solid
Liquid
Gas
Melting
Boiling
25°C
Solid
Liquid
Gas
Current

Phase transition points

Melting point Literature
1454.85 °C
Boiling point Literature
2912.85 °C
Current phase Calculated
Solid

Transition energies

Heat of fusion Literature
0.18116806 eV

Energy required to melt 1 mol at melting point

Heat of vaporization Literature
3.838939 eV

Energy required to vaporize 1 mol at boiling point

Heat of sublimation Literature
4.457688 eV

Energy required to sublime 1 mol at sublimation point

Density

Reference density Literature
8912 kg/m³

At standard conditions

Current density Calculated
8912 kg/m³

At standard conditions

Atomic Spectra

Showing 10 of 28 Atomic Spectra. Sorted by ion charge (ascending).

Lines Holdings ?

IonChargeTotal linesTransition probabilitiesLevel designations
Ni I 0576522522
Ni II +1249208208
Ni III +21285050
Ni IV +3216169169
Ni V +4158215661582
Ni VII +6242424
Ni IX +8382038
Ni X +941041
NIST Lines Holdings →

Levels Holdings ?

IonChargeLevels
Ni I 0288
Ni II +1719
Ni III +2345
Ni IV +3236
Ni V +4324
Ni VI +5273
Ni VII +645
Ni VIII +744
Ni IX +831
Ni X +934
NIST Levels Holdings →
28 Ni 58.6934

Nickel — Atomic Orbital Visualizer

[Ar]4s23d8
Energy levels 2 8 16 2
Oxidation states -2, -1, 0, +1, +2, +3, +4
HOMO 3d n=3 · l=2 · m=-2
Nickel — Atomic Orbital Visualizer Preview
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28 Ni 58.6934

Nickel — Crystal Structure Visualizer

Face-Centered Cubic · Pearson cF4
Experimental
Pearson cF4
Coord. № 12
Packing 74.000%
Nickel — Crystal Structure Visualizer Preview
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Ionic Radii

ChargeCoordinationSpinRadius
+24N/A55.00000000000001 pm
+24N/A49 pm
+25N/A63 pm
+26N/A69 pm
+36low56.00000000000001 pm
+36high60 pm
+46low48 pm

Compounds

Ni
58.693 u
Ni+2
58.693 u
Ni
62.930 u
Ni+3
58.693 u
Ni
61.928 u
Ni
58.934 u
Ni
56.940 u
Ni
55.942 u
Ni
59.931 u
Ni
64.930 u
Ni
60.931 u
Ni
65.929 u
Ni
57.935 u
Ni+2
59.931 u
Ni
52.968 u
Ni
63.928 u

Isotopes (4)

The sulfate and the oxides are important compounds. Natural nickel is a mixture of five stable isotopes; nine other unstable isotopes are known.

Mass numberAtomic mass (u)Natural abundanceHalf-lifeDecay mode
60 Stable59.93078588 ± 0.0000005226.2230% ± 0.0150%Stable
stable
61 Stable60.93105557 ± 0.000000521.1399% ± 0.0013%Stable
stable
62 Stable61.92834537 ± 0.000000553.6346% ± 0.0040%Stable
stable
64 Stable63.92796682 ± 0.000000580.9255% ± 0.0019%Stable
stable
60 Stable
Atomic mass (u) 59.93078588 ± 0.00000052
Natural abundance 26.2230% ± 0.0150%
Half-life Stable
Decay mode
stable
61 Stable
Atomic mass (u) 60.93105557 ± 0.00000052
Natural abundance 1.1399% ± 0.0013%
Half-life Stable
Decay mode
stable
62 Stable
Atomic mass (u) 61.92834537 ± 0.00000055
Natural abundance 3.6346% ± 0.0040%
Half-life Stable
Decay mode
stable
64 Stable
Atomic mass (u) 63.92796682 ± 0.00000058
Natural abundance 0.9255% ± 0.0019%
Half-life Stable
Decay mode
stable

Spectral Lines

Showing 50 of 433 Spectral Lines. Only spectral lines with measured intensity are shown by default.

Wavelength (nm)IntensityIon stageTypeTransitionAccuracySource
385.82968 nm1200Ni Iemission3d9.(2D).4s 1D → 3d9.(2D).4p 3F*MeasuredNIST
380.71402 nm700Ni Iemission3d9.(2D).4s 1D → 3d9.(2D).4p *MeasuredNIST
547.6904 nm180Ni Iemission3d10 1S → 3d9.(2D).4p 1P*MeasuredNIST
383.16908 nm110Ni Iemission3d9.(2D).4s 1D → 3d9.(2D).4p 3P*MeasuredNIST
397.35547 nm110Ni Iemission3d9.(2D).4s 1D → 3d9.(2D).4p 3P*MeasuredNIST
440.1541 nm110Ni Iemission3d8.(3F).4s.4p.(3P*) 5D* → 3d8.4s.(4F).5s 5FMeasuredNIST
471.4417 nm110Ni Iemission3d8.(3F).4s.4p.(3P*) 5G* → 3d8.4s.(4F).5s 5FMeasuredNIST
503.5362 nm100Ni Iemission3d9.(2D).4p 3F* → 3d9.(2D<5/2>).4d 2[9/2]MeasuredNIST
508.0533 nm100Ni Iemission3d9.(2D).4p 3F* → 3d9.(2D<5/2>).4d 2[9/2]MeasuredNIST
464.8652 nm75Ni Iemission3d8.(3F).4s.4p.(3P*) 5G* → 3d8.4s.(4F).5s 5FMeasuredNIST
460.4987 nm65Ni Iemission3d8.(3F).4s.4p.(3P*) 5G* → 3d8.4s.(4F).5s 5FMeasuredNIST
508.111 nm65Ni Iemission3d9.(2D).4p 1F* → 3d9.(2D<3/2>).4d 2[7/2]MeasuredNIST
447.0477 nm55Ni Iemission3d8.(3F).4s.4p.(3P*) 5D* → 3d8.4s.(4F).5s 5FMeasuredNIST
501.7576 nm50Ni Iemission3d8.(3F).4s.4p.(3P*) 5F* → 3d8.4s.(4F).5s 5FMeasuredNIST
478.6535 nm45Ni Iemission3d8.(3F).4s.4p.(3P*) 5G* → 3d8.4s.(4F).5s 5FMeasuredNIST
485.5411 nm45Ni Iemission3d9.(2D).4p 3P* → 3d9.(2D<5/2>).4d 2[3/2]MeasuredNIST
498.0173 nm45Ni Iemission3d8.(3F).4s.4p.(3P*) 5F* → 3d9.(2D<5/2>).4d 2[9/2]MeasuredNIST
490.4412 nm40Ni Iemission3d9.(2D).4p 3P* → 3d9.(2D<5/2>).4d 2[1/2]MeasuredNIST
475.6515 nm30Ni Iemission3d8.(3F).4s.4p.(3P*) 5G* → 3d8.4s.(4F).5s 5FMeasuredNIST
712.2197 nm26Ni Iemission3d9.(2D).4p 3P* → 3d9.(2D<5/2>).5s 2[5/2]MeasuredNIST
468.6213 nm23Ni Iemission3d8.(3F).4s.4p.(3P*) 5G* → 3d8.4s.(4F).5s 5FMeasuredNIST
513.7074 nm23Ni Iemission3d8.(1D).4s2 1D → 3d9.(2D).4p 1P*MeasuredNIST
570.9545 nm23Ni Iemission3d8.(1D).4s2 1D → 3d9.(2D).4p 1F*MeasuredNIST
742.2275 nm23Ni Iemission3d9.(2D).4p 3F* → 3d9.(2D<5/2>).5s 2[5/2]MeasuredNIST
471.5762 nm22Ni Iemission3d8.(3F).4s.4p.(3P*) 5G* → 3d8.4s.(4F).5s 5FMeasuredNIST
480.6993 nm22Ni Iemission3d9.(2D).4p * → 3d8.4s.(4F).5s 3FMeasuredNIST
491.8364 nm22Ni Iemission3d8.(3F).4s.4p.(3P*) 3G* → 3d8.4s.(4F).5s 3FMeasuredNIST
676.7772 nm22Ni Iemission3d10 1S → 3d9.(2D).4p 3P*MeasuredNIST
511.5392 nm21Ni Iemission3d8.(3F).4s.4p.(3P*) 3G* → 3d8.4s.(4F).5s 3FMeasuredNIST
483.1176 nm19Ni Iemission3d8.(3F).4s.4p.(3P*) 5F* → 3d8.4s.(4F).5s 5FMeasuredNIST
446.2455 nm18Ni Iemission3d8.(3F).4s.4p.(3P*) 5D* → 3d8.4s.(4F).5s 5FMeasuredNIST
460.0359 nm18Ni Iemission3d8.(3F).4s.4p.(3P*) 5G* → 3d8.4s.(4F).5s 5FMeasuredNIST
460.6221 nm18Ni Iemission3d8.(3F).4s.4p.(3P*) 5G* → 3d9.(2D<3/2>).4d 2[3/2]MeasuredNIST
501.2443 nm18Ni Iemission3d8.(3F).4s.4p.(3P*) 5F* → 3d8.4s.(4F).5s 5FMeasuredNIST
493.5831 nm16Ni Iemission3d8.(3F).4s.4p.(3P*) 3G* → 3d8.4s.(4F).5s 3FMeasuredNIST
504.8847 nm16Ni Iemission3d9.(2D).4p 1F* → 3d9.(2D<3/2>).4d 2[5/2]MeasuredNIST
575.4656 nm16Ni Iemission3d8.(3P).4s2 3P → 3d9.(2D).4p 1P*MeasuredNIST
664.363 nm16Ni Iemission3d8.(1D).4s2 1D → 3d9.(2D).4p 3P*MeasuredNIST
739.3676 nm16Ni Iemission3d8.(3F).4s2 3F → 3d8.(1D).4s2 1DMeasuredNIST
517.656 nm13Ni Iemission3d9.(2D).4p 1D* → 3d9.(2D<3/2>).4d 2[3/2]MeasuredNIST
559.2262 nm13Ni Iemission3d8.(3P).4s2 3P → 3d8.(3F).4s.4p.(3P*) 3D*MeasuredNIST
625.6355 nm13Ni Iemission3d8.(1D).4s2 1D → 3d9.(2D).4p 3P*MeasuredNIST
568.2199 nm12Ni Iemission3d8.(3F).4s.4p.(3P*) 3F* → 3d9.(2D<3/2>).4d 2[7/2]MeasuredNIST
571.1888 nm10Ni Iemission3d8.(3P).4s2 3P → 3d8.(3F).4s.4p.(3P*) 3F*MeasuredNIST
589.2872 nm10Ni Iemission3d8.(3P).4s2 3P → 3d9.(2D).4p 1P*MeasuredNIST
610.8116 nm10Ni Iemission3d8.(1D).4s2 1D → 3d9.(2D).4p 3D*MeasuredNIST
617.6811 nm10Ni Iemission3d8.(3F).4s.4p.(3P*) 3F* → 3d9.(2D<5/2>).4d 2[9/2]MeasuredNIST
631.4659 nm10Ni Iemission3d8.(3P).4s2 3P → 3d9.(2D).4p 1D*MeasuredNIST
691.4559 nm10Ni Iemission3d8.(3P).4s2 3P → 3d9.(2D).4p 3P*MeasuredNIST
558.7858 nm9Ni Iemission3d8.(3P).4s2 3P → 3d8.(3F).4s.4p.(3P*) 3D*MeasuredNIST

Extended Properties

Covalent Radii (Extended)

Covalent radius (Pyykkö)  
Covalent radius (Pyykkö, double)  
Covalent radius (Pyykkö, triple)  
Covalent radius (Bragg)  

Van der Waals Radii

Batsanov  
Alvarez  
UFF  
MM3  

Atomic & Metallic Radii

Atomic radius (Rahm)  
Metallic radius (C12)  

Numbering Scales

Mendeleev
Pettifor
Glawe

Electronegativity Scales

Ghosh
Miedema
Gunnarsson–Lundqvist
Robles–Bartolotti

Polarizability & Dispersion

Dipole polarizability  
Dipole polarizability (unc.)  
C₆  
C₆ (Gould–Bučko)  

Chemical Affinity

Proton affinity  
Gas basicity  

Miedema Parameters

Miedema molar volume  
Miedema electron density

Supply Risk & Economics

Production concentration
Relative supply risk
Reserve distribution
Political stability (top producer)
Political stability (top reserve)

Phase Transitions & Allotropes

Melting point1728.15 K
Boiling point3186.15 K

Oxidation State Categories

+1 extended
+3 extended
0 extended
+4 extended
−2 extended
−1 extended
+2 main

Advanced Reference Data

Screening Constants (7)
nOrbitalσ
1s0.6474
2p3.9048
2s7.7874
3d15.4705
3p13.915
3s13.039
4s22.2892
Crystal Radii Detail (7)
ChargeCNSpinrcrystal (pm)Origin
2IV69
2IVSQ63
2V77estimated,
2VI83from r^3 vs V plots,
3VILS70from r^3 vs V plots,
3VIHS74estimated,
4VILS62from r^3 vs V plots,
Isotope Decay Modes (54)
IsotopeModeIntensity
482p70%
48B+30%
48B+p
49B+100%
49B+p83.4%
50B+100%
50B+p73%
502p14%
51B+100%
51B+p87.2%
X‑ray Scattering Factors (504)
Energy (eV)f₁f₂
101.37727
10.16171.38064
10.32611.38401
10.49311.3874
10.66281.39079
10.83531.39419
11.01061.39982
11.18861.44104
11.36961.48347
11.55351.52716

Additional Data

Sources

Sources of this element.

Nickel is found as a constituent in most meteorites and often serves as one of the criteria for distinguishing a meteorite from other minerals. Iron meteorites, or siderites, may contain iron alloyed with from 5 percent to nearly 20 percent nickel. Nickel is obtained commercially from pentlandite and pyrrhotite of the Sudbury region of Ontario, a district that produces about 30 percent of the world's supply of nickel.

Other deposits are found in New Caledonia, Australia, Cuba, Indonesia, and elsewhere.

References (1)

References

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Ni

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Nickel

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

License note: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Nickel

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

License note: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Nickel

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Nickel

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Nickel

This section provides all form of data related to element Nickel.

9 PubChem Elements
Nickel

The element property data was retrieved from publications.

Last updated:

Data verified:

Content is reviewed against latest scientific data.